Bimetallic PtPd nanoparticles relying on CoNiO2 and reduced graphene oxide as a most operative electrocatalyst toward ethanol fuel oxidation

Of late, fuel cells have drawn great attentions owing to high-energy demands, fossil fuel depletion and worldwide environmental pollution. Direct ethanol fuel cell (DEFC) constituted as one of the most promising sources of green energy, howbeit the ethanol oxidation reaction (EOR) sluggish kinetic is one of the essential challenges toward the commercialization of DEFCs. Herein, we introduce bimetallic catalyst on CoNiO₂ modified reduced graphene oxide (rGO) to completely exploit the advantages of nano-surface structures as well as the reduction of Pt and Pd loading in fuel cells. With the combined advantages of PtPd, CoNiO₂ and rGO, a significant enhancement in electrocatalytic behavior, stability and CO poisoning tolerance of PtPd have been observed. Regarding the implications, PtPd/CoNiO₂/rGO is greatly preferable than Pt/CoNiO₂/rGO and Pd/CoNiO₂/rGO in terms of high electroactive surface area (ECSA), electro-catalytic activity, and lower onset potential (E_ons) towards the EtOH oxidation in alkaline media. Furthermore, the chronoamperometry curve (CA) illustrated 77% after 3600 s which is dramatically soared compared with the other electrodes (≤40%), demonstrating the high stability of the PtPd bimetallic nanoparticle electrocatalyst. Ultimately, PtPd/CoNiO₂/rGO nanocomposite is found to be an excellent anode electrocatalyst for application in DEFCs.     

Access point selection in the network of Internet of things (IoT) considering the strategic behavior of the things and users

The Journal of Supercomputing - With the expansion in the use of IoT, increasing the efficiency of these networks has become even more significant. Objects need reliable communications at suitable...     

Expression of Main Toll-Like Receptors in Patients with Different Types of Colorectal Polyps and Their Relationship with Gut Microbiota

Abnormal activation of Toll-like receptor (TLRs) signaling can result in colon cancer development. The aim of this study was to investigate the expression of important TLRs in different histological types of colorectal polyps and evaluate their relationship with intestinal microbiota. The expression levels of TLR2, 3, 4, and 5 were analyzed in intestinal biopsy specimens of 21 hyperplastic polyp (HP), 16 sessile serrated adenoma (SSA), 29 tubular adenoma (TA), 21 villous/tubulovillous (VP/TVP) cases, and 31 normal controls. In addition, selected gut bacteria including Streptococcus bovis, Enterococcus faecalis, Enterotoxigenic Bacteroides fragilis (ETBF), Fusobacterium nucleatum, Porphyromonas spp., Lactobacillus spp., Roseburia spp., and Bifidobacterium spp. were quantified in fecal samples using absolute qRT PCR, and, finally, the association between TLRs and these gut microbiota- was evaluated by Spearman’s correlation coefficient. Higher expression of TLR2 and TLR4 in VP/TVP and TA, and lower expression levels of TLR3 and TLR5 in all type of polyps were observed. The differences in TLR expression patterns was not only dependent on the histology, location, size, and dysplasia grade of polyps but also related to the intestinal microbiota patterns. TLR2 and TLR4 expression was directly associated with the F. nucleatum, E. faecalis, S. bovis, Porphyromonas, and inversely to Bifidobacterium, Lactobacillus, and Roseburia quantity. Furthermore, TLR3 and TLR5 expression was directly associated with Bifidobacterium, Roseburia, and Lactobacillus quantity. Our results suggest a possible critical role of TLRs during colorectal polyp progression. An abnormal regulation of TLRs in relation to gut microbial quantity may contribute to carcinogenesis.     

Novel Fault Management Framework Using Markov Chain in Wireless Sensor Networks: FMMC

Wireless Personal Communications - Due to using wireless sensor nodes (WSNs) in inaccessible areas and applying limitations in making nodes to reduce costs, these networks are prone to faults. The...     

Sonification and interaction design in computer games for visually impaired individuals

Multimedia Tools and Applications - Video games are changing how we interact and communicate with each other. They can provide an authentic and collaborative platform for building new communities...     

Sign Language to Sentence Formation: A Real Time Solution for Deaf People

Communication is a basic need of every human being to exchange thoughts and interact with the society. Acute peoples usually confab through different spoken languages, whereas deaf people cannot do so. Therefore, the Sign Language (SL) is the communication medium of such people for their conversation and interaction with the society. The SL is expressed in terms of specific gesture for every word and a gesture is consisted in a sequence of performed signs. The acute people normally observe these signs to understand the difference between single and multiple gestures for singular and plural words respectively. The signs for singular words such as I, eat, drink, home are unalike the plural words as school, cars, players. A special training is required to gain the sufficient knowledge and practice so that people can differentiate and understand every gesture/sign appropriately. Innumerable researches have been performed to articulate the computer-based solution to understand the single gesture with the help of a single hand enumeration. The complete understanding of such communications are possible only with the help of this differentiation of gestures in computer-based solution of SL to cope with the real world environment. Hence, there is still a demand for specific environment to automate such a communication solution to interact with such type of special people. This research focuses on facilitating the deaf community by capturing the gestures in video format and then mapping and differentiating as single or multiple gestures used in words. Finally, these are converted into the respective words/sentences within a reasonable time. This provide a real time solution for the deaf people to communicate and interact with the society.